Inner C-cyanide addition and nucleophilic addition to Ni(II) N-confused porphyrins.
نویسندگان
چکیده
Inner C-cyanide addition and subsequent addition of a methoxy group were observed in the reactions of Ni(II) N-confused tetra(p-tolyl)porphyrin with sodium methoxide and DDQ.
منابع مشابه
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate.
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate, which could be detected by HRMS.
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The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent mol-ecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules. The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 9 شماره
صفحات -
تاریخ انتشار 2003